全文获取类型
收费全文 | 70976篇 |
免费 | 8352篇 |
国内免费 | 6950篇 |
专业分类
电工技术 | 5006篇 |
技术理论 | 67篇 |
综合类 | 8275篇 |
化学工业 | 8470篇 |
金属工艺 | 2259篇 |
机械仪表 | 4711篇 |
建筑科学 | 18902篇 |
矿业工程 | 3746篇 |
能源动力 | 3076篇 |
轻工业 | 4056篇 |
水利工程 | 3720篇 |
石油天然气 | 3431篇 |
武器工业 | 1149篇 |
无线电 | 3944篇 |
一般工业技术 | 6200篇 |
冶金工业 | 2661篇 |
原子能技术 | 463篇 |
自动化技术 | 6142篇 |
出版年
2024年 | 218篇 |
2023年 | 1340篇 |
2022年 | 2137篇 |
2021年 | 2785篇 |
2020年 | 2909篇 |
2019年 | 2206篇 |
2018年 | 1947篇 |
2017年 | 2351篇 |
2016年 | 2682篇 |
2015年 | 2820篇 |
2014年 | 5794篇 |
2013年 | 4374篇 |
2012年 | 5369篇 |
2011年 | 5633篇 |
2010年 | 4537篇 |
2009年 | 4580篇 |
2008年 | 4192篇 |
2007年 | 5035篇 |
2006年 | 4521篇 |
2005年 | 4031篇 |
2004年 | 3475篇 |
2003年 | 2724篇 |
2002年 | 2060篇 |
2001年 | 1621篇 |
2000年 | 1397篇 |
1999年 | 1121篇 |
1998年 | 795篇 |
1997年 | 644篇 |
1996年 | 565篇 |
1995年 | 504篇 |
1994年 | 398篇 |
1993年 | 318篇 |
1992年 | 247篇 |
1991年 | 166篇 |
1990年 | 146篇 |
1989年 | 115篇 |
1988年 | 79篇 |
1987年 | 62篇 |
1986年 | 39篇 |
1985年 | 38篇 |
1984年 | 47篇 |
1983年 | 28篇 |
1982年 | 28篇 |
1981年 | 15篇 |
1980年 | 28篇 |
1964年 | 17篇 |
1961年 | 9篇 |
1959年 | 10篇 |
1957年 | 12篇 |
1951年 | 12篇 |
排序方式: 共有10000条查询结果,搜索用时 171 毫秒
51.
Xinran Zhao Fengxiang Yin Xiaobo He Biaohua Chen Guoru Li 《International Journal of Hydrogen Energy》2021,46(40):20905-20918
To meet the demand of producing hydrogen at low cost, a molybdenum (Mo)-doped cobalt oxide (Co3O4) supported on nitrogen (N)-doped carbon (x%Mo–Co3O4/NC, where x% represents Mo/Co molar ratio) is developed as an efficient bifunctional electrocatalyst for hydrogen evolution reaction (HER) and oxygen evolution reaction (OER). This defect engineering strategy is realized by a facile urea oxidation method in nitrogen atmosphere. Through X-ray diffraction (XRD) refinement and other detailed characterizations, molybdenum ion (Mo4+) is found to be doped into Co3O4 by substituting cobalt ion (Co2+) at tetrahedron site, while N is doped into carbon matrix simultaneously. 4%Mo–Co3O4/NC is the optimized sample to show the lowest overpotentials of 91 and 276 mV to deliver 10 mA cm?2 for HER and OER in 1 M potassium hydroxide solution (KOH), respectively. The overall water splitting cell 4%Mo–Co3O4/NC||4%Mo–Co3O4/NC displays a voltage of 1.62 V to deliver 10 mA cm?2 in 1 M KOH. The Mo4+ dopant modulates the electronic structure of active cobalt ion (Co3+) and boosts the water dissociation process during HER, while the increased amount of lattice oxygen and formation of pyridinic nitrogen due to Mo doping benefits the OER activity. Besides, the smaller grain size owing to Mo doping leads to higher electrochemically active surface area (ECSA) on 4%Mo–Co3O4/NC, resulting in its superior bifunctional catalytic activity. 相似文献
52.
Weiguo Cao Wenjuan Li Liang Zhang Jianfa Chen Shuo Yu Zhuanghong Zhou Yun Zhang Xiaobo Shen Yingxin Tan 《International Journal of Hydrogen Energy》2021,46(52):26693-26707
The explosion venting duct can effectively reduce the hazard degree of a gas explosion and conduct the venting energy to the safe area. To investigate the flame quantitative propagation law of explosion venting with a duct, the effects of hydrogen fraction and explosion venting duct length on jet flame propagation characteristics of premixed H2-air mixtures were analyzed through experiment and simulation. The experiment results under initial conditions of room temperature and 1 atm show that when hydrogen fraction was high enough, part of the unburned hydrogen was mixed with air again to reach an ignitable concentration, resulting in the secondary combustion was easier produced and the duration of the secondary flame increased. With the increase of venting duct length, the flame front distance and propagation velocity increased. Meanwhile, the spatial distribution of pressure field and temperature field, and the propagation process and mechanism of the flame venting with a duct were analyzed using FLUENT software. The variation of the pressure wave and the pressure reflection oscillation law in the explosion venting duct was captured. Therefore, in the industrial explosion venting design with a duct, the hazard caused by the coupling of venting pressure and venting flame under different fractions should be considered comprehensively. 相似文献
53.
以某典型废玻璃回收厂区作为研究对象, 监测和分析了车间及厂区内部的噪声强度、空气颗粒物(PM2.5、PM10) 浓度等环境指标, 点位布设涵盖了车间入口、人工分拣、物料筛分、破碎、干法清洗等关键工艺环节; 其次, 解析了空气颗粒物的组分及形貌特征, 并对其在厂区及车间内部的时空分布特征进行了研究; 此外, 利用噪声控制模型模拟并分析了隔声罩对噪声的控制作用。结果表明, 生产车间中工作态的空气颗粒物浓度显著高于非工作态, 其中干法清洗区浓度最高, 其PM2.5 浓度为3.725 mg/m3, PM10浓度为4.055 mg/m3; 噪声监测结果显示生产车间内噪声强度较高, 达到99.5 dB, 而引入隔声罩后噪声强度可降至67 dB, 结果表明, 隔声罩可有效控制频率为125~1 000 Hz 的噪声。该研究可为废玻璃的绿色、高效回收处置提供理论基础和实践经验。 相似文献
54.
土木工程施工课程作为土木工程及工程管理专业的学科基础课和核心专业课程,在疫情防控期间"停课不停教""停课不停学"的要求下,通过线上平台进行授课。由于土木工程施工课程内容庞杂、综合性强、实践性强,且章节之间关联性较弱,探究既能使学生快速适应,又能保证教学质量的在线教学方法至关重要。以华南某高校土木工程施工课程为例,基于中国大学MOOC、建筑云课、腾讯课堂、QQ群等线上平台讲授教学内容,并运用问卷调查对课程线上教学效果进行评价。结果表明,线上教学为学生提供了丰富灵活的学习方式,显著提高了学生的自主学习能力,扩大了学生的知识面,达到了较好的学习效果。 相似文献
55.
《Ceramics International》2022,48(12):17104-17115
This study reports on the early hydration properties and microstructure evolutions of MgO-activated slag at five curing temperatures (20 °C, 40 °C, 50 °C, 60 °C, and 80 °C) and three MgO types (S-MgO, M ? MgO, and R-MgO). The results indicated that high-temperature curing substantially increased the compressive strength of the specimens. Particularly, the highest strength was obtained at 40 °C and 60 °C for the S-MgO and M-MgO-activated slag specimens, respectively, and the high curing temperature for the R-MgO-activated slag specimen was 40 °C. We focused on the relationship between the mechanical properties, pore structure characteristics, and hydration products. The combination of calcium-silicate-hydrate (C-S-H) gel and Al increased under high-temperature curing conditions. XRD, FT-IR, TG-DTG, and 27Al MAS-NMR results showed a high Al content in the formation of calcium silicate hydrate with Al in its structure (C-A-S-H gel) for the R-MgO-activated slag pastes under high-temperature curing; however, the microstructure was loose owing to the formation of excessive brucite. For the S-MgO-activated slag specimen, the Ca/Si ratio was high, with more Mg2+ penetrating the C-S-H gel interlayer, forming more hydrotalcite-like phases and increasing the chain length of the C-S-H gel. The microstructure showed good compatibility of the hydration products interweaving to form dense microstructures. 相似文献
56.
《Ceramics International》2022,48(17):24454-24461
Enhancement of thermoelectric properties by virtue of decreased electrical resistance through grain boundary engineering is realised in this study. A robust strategy of optimisation of the transport properties by tuning the energy filtering effects at the interfaces by decreasing the interfacial electrical resistance is achieved in LaCoO3 (LCO). This is accomplished by the incorporation of multilayer graphene within the parent LCO matrix containing multi-scale nano/micro grains. The present work has attained a substantial increment in electrical conductivity from a value of 96 Scm-1 for bare LCO to ~5300 Scm-1 at 750 K by incorporating 0.08 wt% multilayer graphene in LCO. No significant change in thermal conductivity is observed due to the presence of multilayer graphene in LCO. A zT of 0.33 at 550 K for 0.08 wt% multi-layer graphene incorporated LCO composite is achieved which is the highest thermoelectric figure of merit value for undoped LCO reported until now. 相似文献
57.
斑衣蜡蝉是一种危害多种林木和果树的重要刺吸性害虫,主要分布于中国、日本、越南、韩国、印度和美国等地。该虫在经济林木中最喜危害葡萄,目前在宁夏地区随着转换寄主,现已扩散到了部分葡萄园,成为贺兰山东麓酿酒葡萄的重要虫害之一。为全面了解其研究进展,本文概述了国内外关于斑衣蜡蝉的寄主植物、形态特征、危害状况、发生规律、生活习性、诱发因素及防治措施等研究现状,以期为防治该虫,寻求进一步研究方向及探讨新的防治途径提供帮助。 相似文献
58.
Jin Wang Mengke Zhang Guanglong Yang Wenwu Song Weiting Zhong Xunyue Wang Minmin Wang Tongming Sun Yanfeng Tang 《Advanced functional materials》2021,31(33):2101532
Highly efficient electrocatalysts composed of earth-abundant elements are desired for water-splitting to produce clean and renewable chemical fuel. Herein, a heteroatomic-doped multi-phase Mo-doped nickel phosphide/nickel sulfide (Mo-NiPx/NiSy) nanowire electrocatalyst is designed by a successive phosphorization and sulfuration method for boosting overall water splitting (both oxygen and hydrogen evolution reactions (HER)) in alkaline solution. As expected, the Mo-NiPx/NiSy electrode possesses low overpotentials both at low and high current densities in HER, while the Mo-NiPx/NiSy heterostructure exhibits high active performance with ultra-low overpotentials of 137, 182, and 250 mV at the current density of 10, 100, and 400 mA cm−2 in 1 m KOH solution, respectively, in oxygen evolution reaction. In particular, the as-prepared Mo-NiPx/NiSy electrodes exhibit remarkable full water splitting performance at both low and high current densities of 10, 100, and 400 mA cm−2 with 1.42, 1.70, and 2.36 V, respectively, which is comparable to commercial electrolysis. 相似文献
59.
60.
由于受到各种因素的影响,广播电视的技术发展仍存在不少问题,亟待进行创新和转型,以提高广播电视工程的技术水平,为广大人民群众提供优质的服务。 相似文献